Because they believed not in God, and trusted not in his salvation:
Psalm 106:24
Yea, they despised the pleasant land, they believed not his word:
Isaiah 7:9
And the head of Ephraim is Samaria, and the head of Samaria is Remaliah's son. If ye will not believe, surely ye shall not be established.
Hebrews 3:12
Take heed, brethren, lest there be in any of you an evil heart of unbelief, in departing from the living God.
Hebrews 3:18
And to whom sware he that they should not enter into his rest, but to them that believed not?
Hebrews 3:19
So we see that they could not enter in because of unbelief.
Hebrews 11:6
But without faith it is impossible to please him: for he that cometh to God must believe that he is, and that he is a rewarder of them that diligently seek him.
1 John 5:10
He that believeth on the Son of God hath the witness in himself: he that believeth not God hath made him a liar; because he believeth not the record that God gave of his Son.
Jude 1:5
I will therefore put you in remembrance, though ye once knew this, how that the Lord, having saved the people out of the land of Egypt, afterward destroyed them that believed not.